Aero-ZnS prepared by physical vapor transport on three-dimensional networks of sacrificial ZnO microtetrapods

• Veaceslav Ursaki,
• Tudor Braniste,
• Victor Zalamai,
• Emil Rusu,
• Vladimir Ciobanu,
• Vadim Morari,
• Daniel Podgornii,
• Pier Carlo Ricci,
• Rainer Adelung and
• Ion Tiginyanu

Beilstein J. Nanotechnol. 2024, 15, 490–499, doi:10.3762/bjnano.15.44

• nanocomposite components with respect to the HOMO and LUMO molecular orbitals of organic compounds subjected to photocatalytic degradation [18][44]. Specific photocatalytic properties of the aero-ZnS materials prepared by physical vapor transport have not been investigated in this paper. However, preliminary

• also needed in view of the large specific surface area inherent to the produced aeromaterials and of the important role played by surface states in shifting the edge of the valence band, improving the visible-light photocatalytic properties, as shown by first-principle investigations in some

• impurities are present in the photoluminescence spectra, including those associated with surface states. Taking into account that, according to previous reports, the surface states, including those related to oxygen species adsorbed at the aeromaterial surface, play an important role in photocatalytic

Prediction of cytotoxicity of heavy metals adsorbed on nano-TiO₂ with periodic table descriptors using machine learning approaches

• Joyita Roy,
• Souvik Pore and
• Kunal Roy

Beilstein J. Nanotechnol. 2023, 14, 939–950, doi:10.3762/bjnano.14.77

• diverse applications. TiO2 has been shown to be a promising material for practical applications because it is highly photoreactive, inexpensive, non-toxic, chemically and biologically inert, and photostable. Also, nano-TiO2 exhibits high specific surface area and anti-corrosion and photocatalytic

• properties [3]. It absorbs UV radiation and shows self-cleaning ability. Nanoparticles have a susceptibility to adsorb other substances to form a mixture leading to a shift of toxicity to living organisms [4]. Hence, many studies have reported cytotoxic characteristics of TiO2 [5][6]. Some NPs are fatal to

Titania nanoparticles for photocatalytic degradation of ethanol under simulated solar light

• Evghenii Goncearenco,
• Iuliana P. Morjan,
• Claudiu Teodor Fleaca,
• Florian Dumitrache,
• Elena Dutu,
• Monica Scarisoreanu,
• Valentin Serban Teodorescu,
• Alexandra Sandulescu,
• Crina Anastasescu and
• Ioan Balint

Beilstein J. Nanotechnol. 2023, 14, 616–630, doi:10.3762/bjnano.14.51

• nanoparticles with dimensions of 40–80 nm, whose number increases with increasing the working pressure. The photocatalytic properties have been investigated regarding the photodegradation of ethanol vapors in Ar with 0.3% O2 using P25 powder as reference under simulated solar light. During the irradiation H2

Plasmonic nanotechnology for photothermal applications – an evaluation

• A. R. Indhu,
• L. Keerthana and
• Gnanaprakash Dharmalingam

Beilstein J. Nanotechnol. 2023, 14, 380–419, doi:10.3762/bjnano.14.33

Bismuth-based nanostructured photocatalysts for the remediation of antibiotics and organic dyes

• Akeem Adeyemi Oladipo and
• Faisal Suleiman Mustafa

Beilstein J. Nanotechnol. 2023, 14, 291–321, doi:10.3762/bjnano.14.26

• plasmonic and photocatalytic properties. The typical and most recently applied bismuth-based nanostructure photocatalysts are depicted in Figure 2. Structural, optoelectronic, and magnetic properties Bismuth's peculiar optical, electronic, and more recently discovered photocatalytic and plasmonic properties

• distorted rhombohedral perovskite structure (ABO3), where A is a corner cation, B is a body-centred middle atom, and O is an oxygen atom or anions attached to the crystal faces. BiFeO3 has strong magnetic and multiferroic, and sufficient photocatalytic properties due to this unique structure. BiFeO3 is an

• absorption range. In addition to improving the photocatalytic properties of the Bi-based host materials, doping them with rare earth elements may also give them special ferroelectric and ferromagnetic properties, as well as electrochemical and luminescent properties. To produce an Er-doped Bi2WO6

Recent trends in Bi-based nanomaterials: challenges, fabrication, enhancement techniques, and environmental applications

• Vishal Dutta,
• Ankush Chauhan,
• Ritesh Verma,
• C. Gopalkrishnan and
• Van-Huy Nguyen

Beilstein J. Nanotechnol. 2022, 13, 1316–1336, doi:10.3762/bjnano.13.109

• energies. Many persistent organic contaminants can be degraded at room temperature through the oxidizing power of VB holes in bismuth oxyhalides [26]. BiOCl, BOI, BiOBr, and composites made from them have been widely reported due to their excellent photocatalytic properties [27][28][29]. However, the

• and deposition and doping of metals and non-metallic elements are the most common doping methods. Metal ions modify the crystal structure of the Bi-based semiconductor photocatalysts or induce defects. Also, the photocatalytic properties may be altered by doping or deposition of metallic components

Role of titanium and organic precursors in molecular layer deposition of “titanicone” hybrid materials

• Arbresha Muriqi and
• Michael Nolan

Beilstein J. Nanotechnol. 2022, 13, 1240–1255, doi:10.3762/bjnano.13.103

• catalytic and photocatalytic properties [46] porous TiO2 frameworks formed by the annealing of titanicone films may serve as catalytic supports [47]. Titanicone films can also be pyrolyzed under Ar to yield conducting TiO2/carbon composite films with important electrochemical applications as electrodes for

Hierarchical Bi₂WO₆/TiO₂-nanotube composites derived from natural cellulose for visible-light photocatalytic treatment of pollutants

• Zehao Lin,
• Zhan Yang and
• Jianguo Huang

Beilstein J. Nanotechnol. 2022, 13, 745–762, doi:10.3762/bjnano.13.66

• − units [22]. The hybridized O 2p and Bi 6s orbitals in the conduction band of the material contribute to the effective transfer of photoinduced electron−hole pairs, resulting in good photocatalytic properties under visible-light irradiation [23][24]. However, there is still room for improvement of the

• Cr2O72− block the active sites of the photocatalyst at pH 3, resulting in rather poor photocatalytic properties. In comparison with the pH 4 and pH 5 conditions, although the adsorption capacities toward HCrO4− and Cr2O72− of the photocatalyst are similar, the photocatalytic reduction reaction of Cr(VI

• , all hierarchical Bi2WO6/TiO2-NT nanocomposites present better photocatalytic properties than those of pure TiO2-NT and Bi2WO6 powder samples, which is attributed to the three-dimensional porous network structures inherited from the original cellulose configuration and the formation of compact

Engineered titania nanomaterials in advanced clinical applications

• Padmavati Sahare,
• Paulina Govea Alvarez,
• Juan Manual Sanchez Yanez,
• Gabriel Luna-Bárcenas,
• Samik Chakraborty,
• Sujay Paul and
• Miriam Estevez

Beilstein J. Nanotechnol. 2022, 13, 201–218, doi:10.3762/bjnano.13.15

• the TiO2 micropatterns (Figure 3) [96]. TiO2 nps are examined in clinical research regarding the ability to destroy organic dirt and inhibit the viability of pathogenic bacteria effectively upon irradiation with visible and UV light [97]. To obtain antimicrobial and photocatalytic properties

Nanoporous and nonporous conjugated donor–acceptor polymer semiconductors for photocatalytic hydrogen production

• Zhao-Qi Sheng,
• Yu-Qin Xing,
• Yan Chen,
• Guang Zhang,
• Shi-Yong Liu and
• Long Chen

Beilstein J. Nanotechnol. 2021, 12, 607–623, doi:10.3762/bjnano.12.50

• substituting the S atom in the benzothiadiazole group with O or Se atoms on the optoelectronic and photocatalytic properties of the CTFs P11 and P12 (Figure 2) [51]. Introducing an O atom boosted the ICT and electron–hole separation due to the higher electron negativity; but it lowered the LUMO level, which as

• photocatalytic properties. PDI-containing polymers, such as P15, normally confer smaller HERs than the others. P18, composed of strong electron-donating and bipyridine segments, rendered the best HER, which was attributed to its enhanced light absorption, better wettability, and more efficient charge separation

Boosting of photocatalytic hydrogen evolution via chlorine doping of polymeric carbon nitride

• Malgorzata Aleksandrzak,
• Michalina Kijaczko,
• Wojciech Kukulka,
• Daria Baranowska,
• Martyna Baca,
• Beata Zielinska and
• Ewa Mijowska

Beilstein J. Nanotechnol. 2021, 12, 473–484, doi:10.3762/bjnano.12.38

• obtaining a highly efficient HER under visible light conditions [28][29]. One of the most effective methods to modify the electronic structure and improve photocatalytic properties, among so many options, seems to be non-metallic doping [30][31][32][33]. For instance, Ma et al. found that the doping of PCN

• transport bridge between the layers of carbon nitride [45][55]. The presented study revealed that the polycondensation of melamine with 2-chloro-4,6-diamino-1,3,5-triazine leads to formation of Cl-doped polymeric carbon nitride. The presented material showed improved photocatalytic properties in the

A review on the biological effects of nanomaterials on silkworm (Bombyx mori)

• Sandra Senyo Fometu,
• Guohua Wu,
• Lin Ma and
• Joan Shine Davids

Beilstein J. Nanotechnol. 2021, 12, 190–202, doi:10.3762/bjnano.12.15

• summarizes some reports on the biological effects of nanomaterials on silkworm and how the application of nanomaterials improves sericulture. Keywords: biological effects; Bombyx mori; nanomaterials; nanotechnology; sericulture; Introduction Nanomaterials have unique optical, electronic, and photocatalytic

• properties which are applied in various fields of science, such as agriculture, cosmetic, food, medicine, and pharmaceutical sectors [1][2][3][4]. Despite the positive contributions of nanomaterials, which include the manufacturing of self-cleaning windows, sunscreen, and thickening agents [5][6], the safety

Unravelling the interfacial interaction in mesoporous SiO₂@nickel phyllosilicate/TiO₂ core–shell nanostructures for photocatalytic activity

• Bridget K. Mutuma,
• Xiluva Mathebula,
• Isaac Nongwe,
• Bonakele P. Mtolo,
• Boitumelo J. Matsoso,
• Rudolph Erasmus,
• Zikhona Tetana and
• Neil J. Coville

Beilstein J. Nanotechnol. 2020, 11, 1834–1846, doi:10.3762/bjnano.11.165

• the core–shell nanostructure and yielded superior photocatalytic properties. Keywords: bandgap energy; core–shell; dye degradation; nickel phyllosilicate; photocatalysts; Introduction Textile dyes and organic compounds are major water pollutants, which create an environmental hazard to aquatic

• NiPS with a sheet-like morphology, which was then used as a catalyst for the hydrogenation of styrene. More recently, Ghiat et al. [39] reported on the photocatalytic properties of nickel phyllosilicates for hydrogen production. Their nickel phyllosilicate, displaying a surface area of 95 m2·g−1, was

• photodegradation of methyl violet dye. For comparison, the photocatalytic properties of pristine TiO2 were also investigated. It is postulated that the controlled surface area of the mesoporous SiO2 as well as the formation of a core–shell network with a flake-like NiPS structure on the surface aided in creating a

Effect of Ag loading position on the photocatalytic performance of TiO₂ nanocolumn arrays

• Jinghan Xu,
• Yanqi Liu and
• Yan Zhao

Beilstein J. Nanotechnol. 2020, 11, 717–728, doi:10.3762/bjnano.11.59

• deposition (ALD) and vacuum evaporation. The effects of the Ag loading position and deposition thickness, and the morphology, structure and composition of Ag-deposited TNC arrays on its optical and photocatalytic properties were studied. The Ag-filled TiO2 (AFT) nanocolumn arrays exhibited higher removal

Fabrication of Ag-modified hollow titania spheres via controlled silver diffusion in Ag–TiO₂ core–shell nanostructures

• Bartosz Bartosewicz,
• Malwina Liszewska,
• Bogusław Budner,
• Marta Michalska-Domańska,
• Krzysztof Kopczyński and
• Bartłomiej J. Jankiewicz

Beilstein J. Nanotechnol. 2020, 11, 141–146, doi:10.3762/bjnano.11.12

• photocatalytic properties of TiO2 and the optical properties of plasmonic NPs [2]. This combination has been shown to extent the photocatalytic activity of TiO2, which is initially limited to UV light [8], to the visible or even to the NIR range of radiation [9]. Recent examples of the fabrication of plasmonic

• obtained composite catalyst exhibits a synergistic effect between the anatase crystalline shell and the AuNPs as well as superb thermal and mechanical stability of the highly dispersed AuNPs. TiO2 HSs decorated with ultrasmall Ag nanocrystallites and exhibiting excellent photocatalytic properties were

Improved adsorption and degradation performance by S-doping of (001)-TiO₂

• Xiao-Yu Sun,
• Xian Zhang,
• Xiao Sun,
• Ni-Xian Qian,
• Min Wang and
• Yong-Qing Ma

Beilstein J. Nanotechnol. 2019, 10, 2116–2127, doi:10.3762/bjnano.10.206

• increase in the amount of •OH and •O2− radicals. Keywords: anatase; chemical state; degradation; photocatalytic properties; S-doping; thermal chemical vapor deposition; titanium dioxide (TiO2); Introduction Anatase TiO2 with a tetragonal symmetry has widely been used for the degradation of organic

• pollutants, as well as in electrocatalysis, solar cells and self-cleaning applications. Its wide use is based on its physicochemical properties, abundance, nontoxicity, environment-friendliness and low cost [1][2][3][4][5][6][7]. The photocatalytic properties of anatase TiO2 crystals are anisotropic since

• state and photocatalytic properties of undoped TiO2, indicating that the temperature is not high enough to effectively achieve S-doping. The effects of S-doping at 250 °C are as follows: (1) S-doping induces a crystal lattice distortion, and the ratio of the lattice parameters c/a varies with the RS/Ti

BiOCl/TiO₂/diatomite composites with enhanced visible-light photocatalytic activity for the degradation of rhodamine B

• Minlin Ao,
• Kun Liu,
• Xuekun Tang,
• Zishun Li,
• Qian Peng and
• Jing Huang

Beilstein J. Nanotechnol. 2019, 10, 1412–1422, doi:10.3762/bjnano.10.139

• degradation product and visible light (λ > 400 nm) was used as the light source for the evaluation of the photocatalytic properties of the prepared BTD composite. The results show that the catalytic performance of the BTD composite under visible-light irradiation is much higher than that of TiO2 or BiOCl

• change to Bi2O3, and Bi2SiO5 and Bi2Ti2O7 will be formed (Figure 1b). At the same time, TiO2 will gradually change from anatase to rutile, resulting in significant degradation of photocatalytic properties [31]. We speculate that the existence of BiOCl leads to the change of the crystal transition

Electronic properties of several two dimensional halides from ab initio calculations

• Mohamed Barhoumi,
• Ali Abboud,
• Lamjed Debbichi,
• Moncef Said,
• Torbjörn Björkman,
• Dario Rocca and
• Sébastien Lebègue

Beilstein J. Nanotechnol. 2019, 10, 823–832, doi:10.3762/bjnano.10.82

• synthesis and the photocatalytic properties of BiOX compounds under three different exposure conditions. Also, transition-metal oxychlorides MOCl (M = Sc, Ti, V, Cr, Fe) systems possess interesting electronic and magnetic properties [21][22][23][24]. Bismuth oxyhalides have been investigated as catalysts

Impact of the anodization time on the photocatalytic activity of TiO₂ nanotubes

• Jesús A. Díaz-Real,
• Geyla C. Dubed-Bandomo,
• Juan Galindo-de-la-Rosa,
• Luis G. Arriaga,
• Janet Ledesma-García and
• Nicolas Alonso-Vante

Beilstein J. Nanotechnol. 2018, 9, 2628–2643, doi:10.3762/bjnano.9.244

• anodization produces vertically oriented, well-ordered nanotubular arrays with high aspect ratio. TiO2 nanotubes (TNTs) produced in this way have been preferred by several groups since they are expected to exhibit better photocatalytic properties than nanoparticles, due to the short electron-diffusion path

• mirrored also in the O 1s spectra. The main peak (O 1s I, 530 eV) is usually attributed to Ti–O bonds, while the secondary one is attributed to surface hydroxy groups, Ti–OH, (O 1s II, 531.6 eV) and is often described as a characteristic of systems with enhanced photocatalytic properties [35]. An increased

Hierarchical heterostructures of Bi₂MoO₆ microflowers decorated with Ag₂CO₃ nanoparticles for efficient visible-light-driven photocatalytic removal of toxic pollutants

• Shijie Li,
• Wei Jiang,
• Shiwei Hu,
• Yu Liu,
• Yanping Liu,
• Kaibing Xu and
• Jianshe Liu

Beilstein J. Nanotechnol. 2018, 9, 2297–2305, doi:10.3762/bjnano.9.214

• . Herein, we synthesized flower-like Ag2CO3/Bi2MoO6 heterostructures, in which Ag2CO3 nanoparticles were evenly anchored on Bi2MoO6 microflowers to construct novel hierarchical heterojunction photocatalysts by via in situ precipitation. The photocatalytic properties of Ag2CO3/Bi2MoO6 was measured regarding

Recent highlights in nanoscale and mesoscale friction

• Andrea Vanossi,
• Dirk Dietzel,
• Andre Schirmeisen,
• Ernst Meyer,
• Rémy Pawlak,
• Thilo Glatzel,
• Marcin Kisiel,
• Shigeki Kawai and
• Nicola Manini

Beilstein J. Nanotechnol. 2018, 9, 1995–2014, doi:10.3762/bjnano.9.190

• assemble more complex nanodevices. Prospects in tuning friction with photo-assisted reactions The influence of light exposure on properties such as friction and adhesion is rarely explored. For instance, it is known that certain surfaces, such as titanium oxide, exhibit photocatalytic properties and might

A visible-light-controlled platform for prolonged drug release based on Ag-doped TiO₂ nanotubes with a hydrophobic layer

• Caihong Liang,
• Jiang Wen and
• Xiaoming Liao

Beilstein J. Nanotechnol. 2018, 9, 1793–1801, doi:10.3762/bjnano.9.170

• from getting into tubes and removing the drugs from the tubes and linkers. Making use of its excellent photocatalytic properties, the organic layer could then be destroyed, allowing the drugs to escape from the linkers and tubes more easily and quickly. Nevertheless, only 2–4% of solar energy is

Perovskite-structured CaTiO₃ coupled with g-C₃N₄ as a heterojunction photocatalyst for organic pollutant degradation

• Ashish Kumar,
• Christian Schuerings,
• Suneel Kumar,
• Ajay Kumar and
• Venkata Krishnan

Beilstein J. Nanotechnol. 2018, 9, 671–685, doi:10.3762/bjnano.9.62

• activity is limited to UV excitation only [35]. Recently, our group has reported a novel RGO–N–CaTiO3 (RGO-NCT) bifunctional photocatalyst which comprises both adsorption and photocatalytic properties [36]. The photocatalytic activity of RGO-NCT photocatalysts was evaluated by studying the degradation of

Fabrication and photoactivity of ionic liquid–TiO₂ structures for efficient visible-light-induced photocatalytic decomposition of organic pollutants in aqueous phase

• Anna Gołąbiewska,
• Marta Paszkiewicz-Gawron,
• Aleksandra Sadzińska,
• Wojciech Lisowski,
• Ewelina Grabowska,
• Adriana Zaleska-Medynska and
• Justyna Łuczak

Beilstein J. Nanotechnol. 2018, 9, 580–590, doi:10.3762/bjnano.9.54

• IL:TBOT (see Table 1). First of all, the samples were analyzed in terms of specific surface area, optical and photocatalytic properties (in a model reaction of phenol degradation in the aqueous phase under visible-light irradiation). The description of all prepared photocatalysts, including the selected

• physicochemical and photocatalytic properties, is shown in Table 1. To understand the nature of the visible-light-induced activity (IL:TBOT molar ratio equal to 1:3 and 1:10), the photocatalysts possessing the highest and lowest activity have been selected for further detailed study (SEM, XPS and XRD). Moreover

• or during synthesis and preparation. Photocatalytic activity The photocatalytic activity of the IL–TiO2 samples was evaluated by phenol degradation induced by visible-light irradiation (using an optical filter with λ > 420 nm). All photocatalysts exhibited better photocatalytic properties than the

Influence of the preparation method on the photocatalytic activity of Nd-modified TiO₂

• Patrycja Parnicka,
• Paweł Mazierski,
• Tomasz Grzyb,
• Wojciech Lisowski,
• Ewa Kowalska,
• Bunsho Ohtani,
• Adriana Zaleska-Medynska and
• Joanna Nadolna

Beilstein J. Nanotechnol. 2018, 9, 447–459, doi:10.3762/bjnano.9.43

• visible light irradiation [8][9][10]. In recent years, the modification with rare earth (RE) metals has proven to be an efficient method to improve the photocatalytic properties of TiO2 and to broaden its absorption to the solar spectrum [8][11][12]. Various Lewis bases can form complexes with RE-modified

• , we presented experimental studies concerning the effect of synthesis methods on lanthanide-modified TiO2. In these studies we compared hydrothermal and sol–gel method. The synthesis method significantly affects the structure, optical, luminescence and photocatalytic properties. It was found that all

• in the corresponding 0.25% Nd-TiO2(SHT) sample (Table 3). The XPS data correspond well with the highest photocatalytic activity exhibited by the 0.25% Nd-TiO2 photocatalyst prepared via HT method (described in detail in the next section). Photocatalytic properties The photocatalytic properties of